Acyl peroxide and photochemical induced reactions of organoboranes with the inert. alpha.,. beta.-unsaturated carbonyl derivatives

HC Brown, GW Kabalka

Index: Brown,H.C.; Kabalka,G.W. Journal of the American Chemical Society, 1970 , vol. 92, p. 712 - 714

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Citation Number: 29

Abstract

On the other hand, derivatives containing one or more alkyl substituents in the terminal group, such as irans-crotonaldehyde (l), trans-3-penten-2-one (ethylideneacetone)(2), mesityl oxide (3), 2-cyclohexen-1-one (4), and 1-cyclohexenyl methyl ketone (5), fail to react under the usual conditions. These derivatives constitute the “icert” group.