Analytical Chemistry

Organic-soluble lanthanide nuclear magnetic resonance shift reagents for sulfonium and isothiouronium salts

TJ Wenzel, J Zaia

Index: Wenzel, Thomas J.; Zaia, Joseph Analytical Chemistry, 1987 , vol. 59, # 4 p. 562 - 567

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Citation Number: 12

Abstract

Lanthanide complexes of the formula [Ln (fod),]-(fod, 6, 6, 7, 7, 8, 8, 8-heptafiuoro-2, 2- dlmethyl-3, 5-octanedlone) are eff ectlve organlc-soluble nuclear magnetlc resonance shlft reagents for sulfonlum and lsothlouronlum salts. The shlft reagent Is formed in solution from Ln (fod), and Ag (fod) or K (fod). The selectlon of Ag (fod) or K (fod) In forming the shift reagent is dependent on the anion of the organic salt. Ag (fod) Is more effectlve wlth halide ...