e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Tetrahedron

The preparations and some properties of mixed aryl-thienyl oligomers and polymers

A Pelter, I Jenkins, DE Jones

Index: Pelter, Andrew; Jenkins, Ieuan; Jones, D. Elfyn Tetrahedron, 1997 , vol. 53, # 30 p. 10357 - 10400

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Citation Number: 75

Abstract

The syntheses by transition metal coupling reactions of a large number of oligomers constructed from benzene and thiophene rings are described. The first use of arylcadmium chlorides for such coupling reactions is reported. The routes chosen allow for rational variation in the modes of linkage, the substitution and the proportions of the two units. The benzene and thiophene rings are always joined in a known order and may bear a wide ...

Bromobenzene Structure

~%

2-iodo-5-phenylthiophene Structure

2-iodo-5-phenyl...

1-Bromooctane Structure

~%

1,4-dibromo-2,5-dioctylbenzene Structure

1,4-dibromo-2,5...

1,4-Dichlorobenzene Structure

1,4-Dichlorobenzene

1-Bromooctane Structure

~%

1 4-DIOCTYLBENZENE Structure

1 4-DIOCTYLBENZENE

Hydroquinone Structure

~%

1,4-DIIODO-2,5-DIBUTOXYBENZENE Structure

1,4-DIIODO-2,5-...

1,4-Dibromobenzene Structure

1,4-Dibromobenzene

chlorozinc(1+),2H-thiophen-2-ide Structure

chlorozinc(1+),...

~72%

2-(4-(Thien-2-yl)phenyl)thiophene Structure

2-(4-(Thien-2-y...

Butyl iodide Structure

Hydroquinone Structure

~59%

1,4-DIBUTOXYBENZENE Structure

1,4-DIBUTOXYBENZENE

1-Bromo-3-chlorobenzene Structure

1-Bromo-3-chlor...

chlorozinc(1+),2H-thiophen-2-ide Structure

chlorozinc(1+),...

~83%

2-(3-chlorophenyl)thiophene Structure

2-(3-chlorophen...

1,3,5-Tribromobenzene Structure

1,3,5-Tribromob...

chlorozinc(1+),2H-thiophen-2-ide Structure

chlorozinc(1+),...

~58%

1,3,5-TRI(THIOPHEN-2-YL)BENZENE Structure

1,3,5-TRI(THIOP...

1,3-Dibromobenzene Structure

1,3-Dibromobenzene

chlorozinc(1+),2H-thiophen-2-ide Structure

chlorozinc(1+),...

~66%

2-(3-thiophen-2-ylphenyl)thiophene Structure

2-(3-thiophen-2...

4-Bromoanisole Structure

chlorozinc(1+),2H-thiophen-2-ide Structure

chlorozinc(1+),...

~79%

2-(4-methoxyphenyl)thiophene Structure

2-(4-methoxyphe...

1,4-Dibromobenzene Structure

1,4-Dibromobenzene

~%

2-bromo-5-[4-(5-bromothiophen-2-yl)phenyl]thiophene Structure

2-bromo-5-[4-(5...