Towards the synthesis of substituted porphyrins by a pyridyl group bearing a reactive functionality

ME Ojaimi, B Habermeyer, CP Gros…

Index: Ojaimi, Maya El; Habermeyer, Benoit; Gros, Claude P.; Barbe, Jean-Michel Journal of Porphyrins and Phthalocyanines, 2010 , vol. 14, # 6 p. 469 - 480

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Citation Number: 4

Abstract

Pyridyl-substituted porphyrins bearing a reactive functionality were prepared via Suzuki cross-coupling reactions in very good yields. These compounds are precursors of new porphyrin architectures able to coordinate two metals: one in the porphyrin core and the second around the pyridyl moiety. During the coupling reactions, a higher reactivity of a chloro picolyl group was evidenced compared to a bromo function on the same reacting ...

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