Canadian journal of chemistry

Lithium aluminium hydride reduction of some triarylvinyl bromides and acetates catalyzed by some transition metal chlorides

CA Obafemi, CC Lee

Index: Obafemi, Craig A.; Lee, Choi Chuck Canadian Journal of Chemistry, 1990 , vol. 68, # 11 p. 1998 - 2000

Full Text: HTML

Citation Number: 7

Abstract

A number of triarylvinyl halides and acetates were reduced with lithium aluminium hydride using various transition metal chlorides as catalysts. The vinylic halides were reduced to the corresponding alkenes while the vinylic acetates were reduced to mixtures of triarylketones

 Related Synthetic Route
tri-p-tolylvinyl bromide Structure

66184-02-9

tri-p-tolylviny...

~96%

Benzene, 1,1,1-(1-ethenyl-2-ylidene)tris(4-methyl- Structure

6629-83-0

Benzene, 1,1,1-...

1-acetoxy-1,2,2-triphenylethene Structure

56019-41-1

1-acetoxy-1,2,2...

~%

Ethanone,1,2,2-triphenyl- Structure

1733-63-7

Ethanone,1,2,2-...

1,2,2-triphenylethanol Structure

2294-93-1

1,2,2-triphenyl...

N/A Structure

96784-47-3

N/A

~%

1,2,2-tris(4-methoxyphenyl)ethanone Structure

61161-13-5

1,2,2-tris(4-me...

1,2,2-tris(4-methoxyphenyl)ethan-1-ol Structure

41299-01-8

1,2,2-tris(4-me...

Chlorotrianisene Structure

569-57-3

Chlorotrianisene

~96%

Benzene,1,1',1''-(1-ethenyl-2-ylidene)tris[4-methoxy- Structure

7109-27-5

Benzene,1,1',1'...

1-bromo-1,2,2-tris(p-methoxyphenyl)ethene Structure

25354-46-5

1-bromo-1,2,2-t...

~96%

Benzene,1,1',1''-(1-ethenyl-2-ylidene)tris[4-methoxy- Structure

7109-27-5

Benzene,1,1',1'...

iodo-tris-(4-methoxy-phenyl)-ethene Structure

114795-34-5

iodo-tris-(4-me...

~95%

Benzene,1,1',1''-(1-ethenyl-2-ylidene)tris[4-methoxy- Structure

7109-27-5

Benzene,1,1',1'...

Bromotriphenylethene Structure

1607-57-4

Bromotriphenylethene

~94%

Triphenylethylene Structure

58-72-0

Triphenylethylene


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