Journal of organometallic chemistry

Multinuclear NMR spectroscopy of (metalla) neopentyl derivatives of tin and mercury

TN Mitchell, B Fabisch

Index: Mitchell, Terence N.; Fabisch, Bodo Journal of Organometallic Chemistry, 1984 , vol. 269, # 3 p. 249 - 254

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Abstract

Abstract Proton, carbon-13, tin-119 and mercury-199 chemical shift and element-metal coupling constant data are presented for compounds of the types SnCH 2 MMe 3) 4, Hg (CH 2 MMe 3) 2, Me 3 SnCH 2 MM 3 and i-BuHgCH 2 MMe 3,(M= C, Si, Ge, Sn). In almost all cases the NMR parameters (shifts or coupling constants) involving corresponding organotin and organomercury species are linearly related, suggesting that tin and mercury chemical ...