Amidines. VII. Hydrolysis and alcoholysis of carboxamides under mild conditions.

…， 荒谷一郎， /田村眞造, S TAMURA

Index: Ono; Araya; Todoriki; Tamura Chemical and Pharmaceutical Bulletin, 1990 , vol. 38, # 7 p. 1824 - 1831

Full Text: HTML

Citation Number: 3

Abstract

Hydrolysis and alcoholysis of carboxamides derived from primary aliphatic amines were achieved under mild conditions. Amide exchange reaction between carboxamides and N 1- acyl-N 1, N 2-di (p-nitrophenyl) formamidines (1) gave N 1-acyl-N 1-alkyl-N 2-(p-nitrophenyl)

 Related Synthetic Route
N/A Structure

130340-73-7

N/A

~74%

Formamide,N-(4-nitrophenyl)- Structure

16135-31-2

Formamide,N-(4-...

N-[2-(ethylamino)ethyl]-p-chlorobenzamide Structure

108093-54-5

N-[2-(ethylamin...

N/A Structure

128915-10-6

N/A

~90%

Formamide,N-(4-nitrophenyl)- Structure

16135-31-2

Formamide,N-(4-...

4-Methylbenzylamine Structure

104-84-7

4-Methylbenzylamine

2-Chlorobenzoyl chloride Structure

609-65-4

2-Chlorobenzoyl...

~%

2-Chloro-N-(4-nitrophenyl)benzamide Structure

55501-45-6

2-Chloro-N-(4-n...

N,N-bis(4-nitrophenyl)methanimidamide Structure

2232-13-5

N,N-bis(4-nitro...

~%

2-Chloro-N-(4-nitrophenyl)benzamide Structure

55501-45-6

2-Chloro-N-(4-n...

N/A Structure

128799-78-0

N/A

~%

2-Chloro-N-(4-nitrophenyl)benzamide Structure

55501-45-6

2-Chloro-N-(4-n...

N/A Structure

130340-58-8

N/A

~%

2-Chloro-N-(4-nitrophenyl)benzamide Structure

55501-45-6

2-Chloro-N-(4-n...

N1-(o-chlorobenzoyl)-N1,N2-di-(p-nitrophenyl)formamidine Structure

130340-63-5

N1-(o-chloroben...

dl-N-(α-phenylpropionyl)-p-methylbenzylamine Structure

130340-59-9

dl-N-(α-phenylp...

~%

2-Chloro-N-(4-nitrophenyl)benzamide Structure

55501-45-6

2-Chloro-N-(4-n...

N/A Structure

130340-77-1

N/A

N,N-bis(4-nitrophenyl)methanimidamide Structure

2232-13-5

N,N-bis(4-nitro...

N/A Structure

128799-78-0

N/A

~74%

4-chloro-N-(4-nitrophenyl)benzamide Structure

39193-07-2

4-chloro-N-(4-n...

N/A Structure

130340-58-8

N/A

Detail
N-(p-Chlorobenzoyl)-p-methylbenzylamine Structure

41882-23-9

N-(p-Chlorobenz...

N/A Structure

128799-78-0

N/A

~%

4-chloro-N-(4-nitrophenyl)benzamide Structure

39193-07-2

4-chloro-N-(4-n...

N/A Structure

130117-94-1

N/A

Detail
N-(p-Chlorobenzoyl)-p-methylbenzylamine Structure

41882-23-9

N-(p-Chlorobenz...

N/A Structure

128799-78-0

N/A

~%

4-chloro-N-(4-nitrophenyl)benzamide Structure

39193-07-2

4-chloro-N-(4-n...

N/A Structure

130117-94-1

N/A

Detail
N-(p-Chlorobenzoyl)-p-methylbenzylamine Structure

41882-23-9

N-(p-Chlorobenz...

N/A Structure

128799-78-0

N/A

~%

4-chloro-N-(4-nitrophenyl)benzamide Structure

39193-07-2

4-chloro-N-(4-n...

N/A Structure

130117-94-1

N/A


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