Kinetic Study on SNAr Reaction of 1-(Y-Substituted-phenoxy)-2, 4-dinitrobenzenes with Cyclic Secondary Amines in Acetonitrile: Evidence for Cyclic Transition-State …

IH Um, MY Kim, TA Kang, JM Dust

Index: Crampton, Michael R.; Robotham, Ian A. Journal of Physical Organic Chemistry, 2013 , vol. 26, # 12 p. 1084 - 1089

Full Text: HTML

Citation Number: 8

Abstract

... The Journal of Organic ... J. Org ... uncatalyzed and catalyzed reactions, respectively, while the Yukawa–Tsuno plots for the reactions of 1a–1h with piperidine result in excellent linear correlations with ρ Y = 1.85 and r = 0.27 for the uncatalyzed reaction and ρ Y = 0.73 and r = 0.23 ...