Comments on different synthetic methods for the preparation of diammine and bis (amine) organodicarboxylatoplatinum (II) complexes

…, C Caldiroia, S Spinelli, M Valsecchi

Index: Pasini, A.; Caldirola, C.; Spinelli, S.; Valsecchi, M. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1993 , vol. 23, p. 1021 - 1060

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Citation Number: 21

Abstract

Abstract Various synthetic routes to [PtA2 (dic)](1, A= NH3, amine, or 1/2 diamine; dic, chelated organodicarboxylate) are reviewed and discussed in the light of the literature and our experience. Emphasis is given to yields and purity of the intermediates and the products. A simple purification procedure is described. The mechanism of the reaction between bis (amine) dihydroxoplatinum (II) complexes and dicarboxylic acids has been investigated by ...