Reaction of carbonyl compounds with trialkylsilyl phenylselenide and tributylstannyl hydride under radical conditions

Y Nishiyama, H Kajimoto, K Kotani…

Index: Nishiyama, Yutaka; Kajimoto, Hiroyuki; Kotani, Kazuya; Nishida, Takuma; Sonoda, Noboru Journal of Organic Chemistry, 2002 , vol. 67, # 16 p. 5696 - 5700

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Citation Number: 7

Abstract

A novel method for the hydrosilylation of carbonyl compounds has been developed. When carbonyl compounds were allowed to react with trimethylsilyl phenylselenide and tributylstannyl hydride in the presence of a catalytic amount of AIBN as the radical initiator, hydrosilylation of the carbonyl compounds efficiently proceeded to give the corresponding silyl ethers in moderate to good yields. In the absence of carbonyl compounds, the ...

~29%

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