The reaction between N, N-dialkylhydroxylamines and sulphinyl chlorides

MR Banks, RF Hudson

Index: Banks, Malcolm R.; Hudson, Robert F. Journal of the Chemical Society, Chemical Communications, 1985 , # 12 p. 799 - 800

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Citation Number: 3

Abstract

The reaction of N, N-dialkylhydroxylamines with sulphinyl chlorides proceeds via an O- sulphinylated hydroxylamine intermediate, which has been isolated and characterised by nmr spectroscopy; rearrangement of this intermediate to the sulphonamide has been shown to involve an aminyl radical.

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