Water soluble phosphines: Part XV. Syntheses of multiply functionalized and chiral phosphine ligands by Pd-catalyzed P C and C C coupling reactions

…, T Nickel, M Tepper, O Stelzer, WS Sheldrick

Index: Brauer, David J.; Hingst, Martin; Kottsieper, Konstantin W.; Liek, Christian; Nickel, Thomas; Tepper, Michael; Stelzer, Othmar; Sheldrick, William S. Journal of Organometalic Chemistry, 2002 , vol. 645, # 1-2 p. 14 - 26

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Citation Number: 83

Abstract

Phosphine ligands containing mono-and multiply substituted aromatic substituents (1–13, 19a and 19b) are accessible in high yields by palladium-catalyzed P C coupling reactions between primary, secondary or disecondary phosphines and iodo-or bromoaromatic compounds. The reaction is of broad applicability and compatible with electron donor or electron acceptor substituents in ortho, meta or para position to the halogen in the ...