e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Structure and stability of 2σ/1σ* three??electron??bonded radical cations from 1, n??bis (alkylthio) alkanes in aqueous solutions

E Anklam, KD Asmus, H Mohan

Index: Anklam, Elke Synthesis, 1987 , # 9 p. 841 - 843

Full Text: HTML

Citation Number: 19

Abstract

Abstract A large number of 1, n-bis (alkylthio) alkanes, R′ S (CH 2) n SR ″, was investigated by pulse radiolysis in aqueous solutions. The sulphur-centred radical cations, which were obtained on oxidation of the dithia compounds by· OH radicals, are stabilized via

2-Propanethiol Structure

1,3-Dibromopropane Structure

1,3-Dibromopropane

~47%

1,3-bis(propan-2-ylsulfanyl)propane Structure

1,3-bis(propan-...

1-bromo-3-propan-2-ylsulfanylpropane Structure

1-bromo-3-propa...

Methyl mercaptan Structure

Methyl mercaptan

1,3-Diiodopropane Structure

1,3-Diiodopropane

~43%

1,3-bis(methylsulfanyl)propane Structure

1,3-bis(methyls...

1-iodo-3-methylsulfanylpropane Structure

1-iodo-3-methyl...

Cyclohexanethiol Structure

Cyclohexanethiol

1,4-Dichlorobutane Structure

1,4-Dichlorobutane

~39%

Cyclohexane,[(4-chlorobutyl)thio]- Structure

Cyclohexane,[(4...

1,4-bis(cyclohexylthio)butane Structure

1,4-bis(cyclohe...

1,3-Dichloropropane Structure

1,3-Dichloropropane

Ethanethiol Structure

~50%

1-chloro-3-ethylsulfanylpropane Structure

1-chloro-3-ethy...

1,3-Propanediylbis(ethyl sulfide) Structure

1,3-Propanediyl...

Methyl mercaptan Structure

Methyl mercaptan

1,4-Dichlorobutane Structure

1,4-Dichlorobutane

~37%

Butane,1,4-bis(methylthio)- Structure

Butane,1,4-bis(...

1-chloro-4-methylsulfanylbutane Structure

1-chloro-4-meth...

Methyl mercaptan Structure

Methyl mercaptan

1,5-Dichloropentane Structure

1,5-Dichloropentane

~0%

Pentane, 1,5-bis (methylthio)- Structure

Pentane, 1,5-bi...

1-chloro-5-methylthiopentane Structure

1-chloro-5-meth...

1,5-Dibromopentane Structure

1,5-Dibromopentane

Methyl mercaptan Structure

Methyl mercaptan

~0%

Pentane, 1,5-bis (methylthio)- Structure

Pentane, 1,5-bi...

1-bromo-5-methylthiopentane Structure

1-bromo-5-methy...

1,4-Dichlorobutane Structure

1,4-Dichlorobutane

Ethanethiol Structure

~0%

1-ethylsulfanyl-4-chloro-butane Structure

1-ethylsulfanyl...

Butane,1,4-bis(ethylthio)- Structure

Butane,1,4-bis(...

2-Propanethiol Structure

1,3-Dibromopropane Structure

1,3-Dibromopropane

~0%

1,3-bis(propan-2-ylsulfanyl)propane Structure

1,3-bis(propan-...

1-bromo-3-propan-2-ylsulfanylpropane Structure

1-bromo-3-propa...

1,3-Diiodopropane Structure

1,3-Diiodopropane

2-Propanethiol Structure

~0%

1,3-bis(propan-2-ylsulfanyl)propane Structure

1,3-bis(propan-...

(3-iodopropyl)(isopropyl)sulfane Structure

(3-iodopropyl)(...

1,5-Dichloropentane Structure

1,5-Dichloropentane

Ethanethiol Structure

~0%

1-chloro-6-ethylthiopentane Structure

1-chloro-6-ethy...

3,9-Dithiaundecane Structure

3,9-Dithiaundecane

1,5-Dibromopentane Structure

1,5-Dibromopentane

Ethanethiol Structure

~0%

3,9-Dithiaundecane Structure

3,9-Dithiaundecane

(5-bromopentyl)(ethyl)sulfane Structure

(5-bromopentyl)...

1,5-Diiodopentane Structure

1,5-Diiodopentane

Ethanethiol Structure

~0%

3,9-Dithiaundecane Structure

3,9-Dithiaundecane

ethyl(5-iodopentyl)sulfane Structure

ethyl(5-iodopen...

1-Propanethiol Structure

1,4-Dichlorobutane Structure

1,4-Dichlorobutane

~0%

propyl 4-chlorobutyl sulfide Structure

propyl 4-chloro...

1,4-bis(propylsulfanyl)butane Structure

1,4-bis(propyls...

Methyl mercaptan Structure

Methyl mercaptan

1,4-Dichlorobutane Structure

1,4-Dichlorobutane

~0%

Butane,1,4-bis(methylthio)- Structure

Butane,1,4-bis(...

1-chloro-4-methylsulfanylbutane Structure

1-chloro-4-meth...

Kinetic acidity of cyclopropyl sulphones

[Kirmse, Wolfgang; Mrotzeck, Uwe Journal of the Chemical Society, Chemical Communications, 1987 , # 10 p. 709 - 710]