Organometallics

The germanium-hydrogen bond dissociation energies of organogermanes. A laser-induced photoacoustic study

KB Clark, D Griller

Index: Clark, K. Brady; Griller, David Organometallics, 1991 , vol. 10, p. 746 - 750

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Citation Number: 67

Abstract

The Ge-H bond dissociation energies (BDE's) of severai alkyl-and aryl-substituted germanium hydrides have been measured in hydrocarbon solution at room temperature by a photoacoustic technique. The BDE's of these hydrides are unaffected by alkyl substitution when compared to those for GeH4 and are in the range of 81.6-82.6 kcal/mol. Aryl substitution leads to a slightly weakened Ge-H bond (79.2-80.2 kcal/mol) in the cases of ...

Protolyses of (CH 3) 3 SnM (CH 3) 3 (M= Sn, Ge, Si, C)

[Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R. Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24]

Electron Affinities and Gas-Phase Acidities of Organogermani...

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Protolyses of (CH 3) 3 SnM (CH 3) 3 (M= Sn, Ge, Si, C)

[Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R. Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24]

The first example of Ge-Ge and Sn-Sn bond cleavage by arylma...

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