Journal of the American Chemical Society

Allylic Rearrangements. XXXV. The Reactions of the Sodium Derivative of Allylbenzene in n-Pentane with Methanol, Alkyl and Allylic Halides1a

RY Mixer, WG Young

Index: Mixer; Young Journal of the American Chemical Society, 1956 , vol. 78, p. 3379,3381

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Citation Number: 25

Abstract

The reactions of the sodium derivative of allylbenzene,[C8HsCH-CH2-CH2] e, in n-pentane with methanol, methyl bromide, n-amyl chloride, allyl chloride, allyl iodide, l-chloro-2-butene, 3-chloro-l-butene, 1-bromo-2-butene and 3-bromo-1 butene have been studied and compared to the analogous reactions in liquid ammonia. The action of methanol with the sodium derivative of 1-phenylcyclohexene has also been studied in liquid ammonia. A ...