The chemo-selective reduction of fluorinated halogenoesters with sodium borohydride. Fluorinated halogenoalkanols and their (meth) acrylates

O Paleta, A Danda, L Štěpán, J Kvíčala…

Index: Paleta, O.; Danda, A.; Stepan, L.; Kvicala, J.; Dedek, V. Journal of Fluorine Chemistry, 1989 , vol. 45, p. 331 - 348

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Citation Number: 15

Abstract

Abstract Several chlorofluoroalkanols R F-CH 2 OH (RF is CF 3-CFCl, CF 2 Cl-CF 2, CF 2 Cl- CFCl and CF 2 Cl) and their methacrylates or acrylates were synthesized. The corresponding polymeric methacrylates have properties of highly-sensitive electron-beam and X-ray resists for microlithograhy. The main step in the syntheses, which start from halogenoalkanes R F-CCl 3, is the chemo-selective reduction of halogenoesters with ...