Synthesis and structural characterization of carbon-centered tris (pentafluorophenyl) silyl derivatives

…, VP Ananikov, VM Danilenko, VA Tartakovsky

Index: Dilman, Alexander D.; Arkhipov, Dmitry E.; Korlyukov, Alexander A.; Ananikov, Valentine P.; Danilenko, Vitalij M.; Tartakovsky, Vladimir A. Journal of Organometallic Chemistry, 2005 , vol. 690, # 16 p. 3680 - 3689

Full Text: HTML

Citation Number: 13

Abstract

A general method for the synthesis of carbon-centered tris (pentafluorophenyl) silyl derivatives (RSi (C6F5) 3) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The crystal structures of obtained compounds were studied by X-ray diffraction analysis (7 structures). The peculiarities of crystal packing were analyzed by means of DFT calculations.