Synthetic Communications

A new and Facile Method for Synthesis of AZA-Wittig Reagents under Microwave Irradiation

M Chen, G Yuan, S Yang

Index: Chen, Mindong; Yuan, Guangpu; Yang, Shiyan Synthetic Communications, 2000 , vol. 30, # 7 p. 1287 - 1294

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Citation Number: 4

Abstract

Abstract We report a simple and quick synthetic method of some new Aza-Wittig reagents in anhydrous acetonitrile under microwave irradiation. 1-Substituted aryl-4-ethoxycarbonyl-5-[( triphenylphosphoranylidene) amino]-1, 2, 3-triazoles can be obtained within three minutes by microwave irradiation to the mixture of 1-substituted aryl-4-ethoxycarbonyl-5-amino-1, 2, 3-triazoles, triphenylphosphine, hexachloroethane and triethylamine. The products were ...