Journal of organometallic chemistry

Reaction of 2, 4, 6-tri-t-butylphenyllithium with bromotrichlorosilane. Generation of trichlorosilyllithium, LiSiCl3

H Oehme, H Weiss

Index: Oehme, H.; Weiss, H. Journal of Organometallic Chemistry, 1987 , vol. 319, p. C16 - C18

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Citation Number: 23

Abstract

Trichlorosilyllithium, LiSiCl 3 , is formed by reaction of bromotrichlorosilane with 2,4,6-tri-t-butylphenyllithium or mesityllithium. It is detected as trichlorosilane which is obtained by protonation and characterized by a 29 Si NMR shift of 30.9 ppm. Its stability is evaluated. ... Cl 6 Journal of Organometallic Chemistrc, 319 (1987) C1618 Elsevier Sequoia SA., Lausanne Printed in The Netherlands Preliminary communication REACTION OF 2,4,6-TRI-t-BUTYLPHENYLLITHIUM WITH ...