Science China Chemistry

Synthesis, structure and property of one porous Zn (salen)-based metal-metallosalen framework

YW Peng, CF Zhu, Y Cui

Index: Peng, Yongwu; Zhu, Chengfeng; Cui, Yong Science China Chemistry, 2014 , vol. 57, # 1 p. 107 - 113

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Citation Number: 3

Abstract

Abstract Chiral Schiff-base ligand L was synthesized through six steps in good overall yield from readily available 2-tert-butylphenol and was used to construct one chiral porous metal- metallosalen framework,[Zn 5 (µ 3-OH) 2 (ZnL) 4 (H 2 O) 2]· 18H 2 O (1, L= 5′, 5 ″-(1 E, 1′ E)-(1 R, 2 R)-cyclohexane-1, 2-diylbis (azan-1-yl-1-ylidene) bis (methan-1-yl-1-ylidene) bis (3′-tert-butyl-4′-hydroxybiphenyl-4-carboxylic acid), under mild reaction conditions. ...