Journal of the Chemical Society (Resumed)

594. The conversion of carbamoylmethyl thiolsulphates into thio-oxamides; a new variant of the Willgerodt–Kindler reaction

B Milligan, JM Swan

Index: Milligan; Swan Journal of the Chemical Society, 1959 , p. 2969,2976

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Citation Number: 12

Abstract

By heating thiolsulphates with amines we hoped initially to synthesise sulphenamides according to the equation R* S* SO, Na+ R'vNH, __+ RS-NHR'+ NaHSO,. Such sulphenamides derived from (I) would be hardly distinguishable by analysis (two hydrogen