Chemistry–An Asian Journal

Heterogeneous Aromatic Amination of Aryl Halides with Arylamines in Water with PS??PEG Resin??Supported Palladium Complexes

Y Hirai, Y Uozumi

Index: Hirai, Yoshinori; Uozumi, Yasuhiro Chemistry - An Asian Journal, 2010 , vol. 5, # 8 p. 1788 - 1795

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Citation Number: 17

Abstract

Abstract Catalytic aromatic amination is achieved in water under heterogeneous conditions by the use of immobilized palladium complexes coordinated with the amphiphilic polystyrene-poly (ethylene glycol) resin-supported di (tert-butyl) phosphine ligand. Aromatic amination of aryl halides with diphenylamine and N, N-double arylation of anilines with bromobenzene were found to proceed in water with broad substrate tolerance to give the ...