Organometallics

Synthesis and chemistry of thiagermiranes

T Tsumuraya, S Sato, W Ando

Index: Tsumuraya, Takeshi; Sadao, Sato; Ando, Wataru Organometallics, 1989 , vol. 8, p. 161 - 167

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Citation Number: 26

Abstract

1, Qthiagermirane (18). Photolysis of thiagermirane 18 yields dimesitylgermylene (16) and adamantanethione (3) derived from germathiocarbonyl ylide 22. Oxidation of thiagermirane 18 by mCPBA gives 3-(2-adamantyl)-4, 4-dimesityl-l, 2, 4-oxathiagermetane S-oxide (27). X- ray analyses were done for thiagermirane 18 and 1, 2, 4-oxathiagermetane S-oxide 27.