The Base-Catalyzed Decomposition of N-Nitroso-N-cyclopentylurethan1

FW Bollinger, FN Hayes, S Siegel

Index: Bollinger et al. Journal of the American Chemical Society, 1953 , vol. 75, p. 1729

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Citation Number: 4

Abstract

(2) Merck & Co., Inc., Rahway, New Jersey.(3) FW Bollinger, FN Hayes and S. Siegel, THIS JOURNAL,'72, 5592 (1950). by methanol or water (formed in the reaction) and (2) a displacement of. cyclopentyldiazo€ ate ion by methoxide or hydroxide ion. The five- membered carbon ring skeleton does not undergo contraction in this decomposition. This is in agreement with the work of Hiickel, et al., 4 who on diazotization of cyclopentylamine in ...