Neue Ergebnisse zur Stereoselektivität der Ketoketen??Dimerisierung

…, M Slopianka, U Fastabend, K Drechsler…

Index: Dehmlow, Eckehard V.; Pickardt, Joachim; Slopianka, Marion; Fastabend, Uwe; Drechsler, Katharina; Soufi, Johanna Liebigs Annalen der Chemie, 1987 , p. 377 - 379

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Abstract

New R dbr 011 tbe S temmktd'tyofKetoketmeDimeriudoes Alkylation of 2, Uisubstituted 1, 3- cyclobutanediones results in tetraalkylcyclobutanediones with nutts-positioned large resi- dues. Thermal dimerization of hpropylmethylketene gives cis-dimer 4r as major product, whereas methylneopentyketene yields more of the hum-isomer 5b. The results an discussed in connection with a L2,+ $?. I process.