e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Synthesis and Reactions of o-Naphthothioquinone Methides
R Okazaki, K Sunagawa, M Kotera, KT Kang…
Index: Okazaki, Renji; Sunagawa, Kazuhiko; Kotera, Mitsuharu; Kang, Kyung-Tae; Inamoto, Naoki Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 1 p. 243 - 246
Photochemical reactions of naphtho [1, 2-c][1, 2] dithiole-3-thione (7), naphtho [2, 1-c][1, 2] dithiole-1-thione (10), and naphtho [2, 3-c][1, 2] dithiole-3-thione (16) with cyclohexene and 2, 3-dimethyl-2-butene afford the corresponding naphthothioquinone methides. The thioquinone methide from 7 exists only as a monomeric form and is the first isolable o- thioquinone methide, while that from 16 exists as a dimer of [4+ 4] type in the solid state ...
![naphtho[1,2-c][1,2]dithiole-3-thione Structure](https://image.chemsrc.com/caspic/112/62216-53-9.png)
![2-(3a,4,5,6,7,7a-hexahydrobenzo[d][1,3]dithiol-2-ylidene)naphthalene-1-thione Structure](https://image.chemsrc.com/caspic/064/62216-54-0.png)
![3a,3a'',4,4'',5,5'',6,6'',7,7a,7'',7a''-dodecahydrodispiro[benzo[d][1,3]dithiole-2,14'-dinaphtho[2,3-c:2',3'-g][1,2]dithiocine-15',2''-benzo[d][1,3]dithiole] Structure](https://image.chemsrc.com/caspic/217/81263-85-6.png)
![3a,4,5,6,7,7a-hexahydrospiro[benzo[d][1,3]dithiole-2,3'-naphtho[2,3-c][1,2]dithiole] Structure](https://image.chemsrc.com/caspic/255/81263-84-5.png)