Controlled Site-Selective Reaction of γ, γ-Dialkoxyallylic Zirconium Species with Carbonyl Compounds: A New Method for the Construction of g em- …

H Ito, H Kuroi, H Ding, T Taguchi

Index: Ito; Kuroi; Ding; Taguchi Journal of the American Chemical Society, 1998 , vol. 120, # 26 p. 6623 - 6624

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Citation Number: 25

Abstract

Carbon-carbon bond-forming reactions of allylic organometallics with electrophiles have been recognized as one of the most fundamental means in organic synthesis, and a number of applications for the construction of biologically active molecules have been reported. 1 Normally, allylic organometallics react with electrophiles at the R-or γ-position of a metal center. We have reported the carbon-carbon bond-forming reactions by use of the allylic ...