Formation of Aminomonopersulfuric Acid by the Interaction of Fuming Sulfuric Acid and Hydrogen Azide

HEM Specht, AW Browne…

Index: Specht, H. E. M.; Browne, A. W.; Sherk, K. W. Journal of the American Chemical Society, 1939 , vol. 61, p. 1083 - 1086

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Citation Number: 6

Abstract

Summary The methyl derivatives of borine trimethylammine have been prepared and characterized. In these compounds the stability decreases as the number of methyl groups increases; all are less stable than borine trimethylammine itself. Methylation of borine trimethylammine increases the rate at which hydrogen chloride attacks the remaining BH links to produce hydrogen. Only in the trimethyl derivative is the BN link broken by ...