Organic letters

De Novo Formal Synthesis of (-)-Apicularen A via an Iterative Asymmetric Hydration Sequence

M Li, GA O'Doherty

Index: Organic Letters, , vol. 8, # 26 p. 6087 - 6090

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Citation Number: 60

Abstract

... Volume: Page: ... Organic Letters. ... To access useful quantities of dienoate 9, an efficient five-step approach was developed (Scheme 3). The route featured the KAPA-promoted alkyne zipper reaction 8 and the Ph 3 P-promoted ynoate to dienoate isomerization ...