Carbon-carbon double bond cleavage using solid-supported potassium permanaganate on silica gel

J Tercio, B Ferreira, WO Cruz, PC Vieira…

Index: Ferreira, J. Tercio B.; Cruz, W. O.; Vieira, P. C.; Yonashiro, M. Journal of Organic Chemistry, 1987 , vol. 52, # 16 p. 3698 - 3699

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Citation Number: 48

Abstract

To overcome this problem, phase-transfer catalysis4 and cyclic polyethers5 have been used to solubilize the oxidant into the organic phase. A great number of organic reactions using solid-supported reagents have been developed in the past, 6 where permanganate oxidations play a main role. Potassium permanganate supported on molecular sieves7 or silica gel* have been used to oxidize alcohols to carbonyl compounds and to convert y- ...