Cleavage of carbon-carbon triple bond of alkyne via hydroiminoacylation by Rh (I) catalyst

CH Jun, H Lee, CW Moon, HS Hong

Index: Jun; Lee; Choong Woon Moon; Hong Journal of the American Chemical Society, 2001 , vol. 123, # 35 p. 8600 - 8601

Full Text: HTML

Citation Number: 57

Abstract

The cleavage of carbon-carbon bonds has become one of the most challenging subjects in organic chemistry. 1 Despite remarkable progress in this area, alkyne cleavage has been demonstrated only on a few examples including alkyne-ligand scission on metal complexes2 and oxidative cleavage3 in addition to alkyne metathesis. 4 Moreover, most of them are not efficient enough to be utilized for synthetic purpose. Therefore, we attempted ...

~94%

~91%

~80%

~89%

~25%

~31%

~92%

AuCl 3/AgSbF 6-catalyzed rapid epoxide to carbonyl rearrange...

[Gudla, Vanajakshi; Balamurugan, Rengarajan Tetrahedron Letters, 2012 , vol. 53, # 39 p. 5243 - 5247]

The reaction of α, β-epoxy sulfoxides with lithium dimethylc...

[Satoh, Tsuyoshi; Sugimoto, Atsushi; Itoh, Masayuki; Yamakawa, Koji Tetrahedron Letters, 1989 , vol. 30, # 9 p. 1083 - 1086]

Intermolecular hydroamination of alkynes catalyzed by dimeth...

[Angewandte Chemie - International Edition, , vol. 38, # 22 p. 3389 - 3391]

Probes of the active site of norepinephrine N-methyltransfer...

[Grunewald, Gary L.; Monn, James A.; Rafferty, Michael F,; Borchardt, Ronald T.; Krass, Polina Journal of Medicinal Chemistry, 1982 , vol. 25, # 10 p. 1248 - 1250]

Estrogenic diazenes: heterocyclic non-steroidal estrogens of...

[Ghosh, Usha; Ganessunker, Deshanie; Sattigeri, Viswajanani J.; Carlson, Kathryn E.; Mortensen, Deborah J.; Katzenellenbogen, Benita S.; Katzenellenbogen, John A. Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 4 p. 629 - 657]