Russian journal of general chemistry

Spectroscopic and electrochemical properties of dichlorodiimine complexes of Au (III) and Pt (II) with 1, 4-diazine derivatives of o-phenanthroline

MA Ivanov, MV Puzyk, KP Balashev

Index: Ivanov; Puzyk; Balashev Russian Journal of General Chemistry, 2006 , vol. 76, # 6 p. 843 - 848

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Citation Number: 4

Abstract

Abstract A series of dichlorodiimine complexes [M (NN) Cl 2] z of Au (III) and Pt (II) with 1, 4- derivatives of o-phenanthroline [(NN)= o-phenanthroline (phen), dipyrido [f, h] quinoxaline (dpq), dipyrido [a, c] phenazine (dppz), 6, 7-dicyanodipyrido [f, h] quinoxaline (dicnq)] were prepared and characterized by 1 H NMR, electronic absorption, and emission spectroscopy and by cyclic voltammetry. In all the complexes, the 3 (π-π*)-type transition is the spin- ...