Tetrahedron letters

Palladium catalysed Heck and enantioselective allylic substitution reactions using reverse phase silica supports

MS Anson, AR Mirza, L Tonks, JMJ Williams

Index: Anson, Michael S.; Mirza, Amin R.; Tonks, Louise; Williams, Jonathan M.J. Tetrahedron Letters, 1999 , vol. 40, # 39 p. 7147 - 7150

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Citation Number: 57

Abstract

The use of reverse phase controlled-pore glass beads in Heck reactions affords the products with low levels of palladium leaching. Additionally, an enantioselective palladium catalysed allylic substitution reaction has been achieved with high enantiomeric excess and a low level of leaching