Inorganic chemistry

Preparation of the nitryl salts ON (Cl) F+ AsF6-, ON (CF3) F+ AsF6-, and HON (CH2) CF3+ SbF6-and crystal structure of HON (CH2) CF3+ AsF6

R Minkwitz, D Bernstein, H Preut, P Sartori

Index: Minkwitz, Rolf; Bernstein, Dirk; Preut, Hans; Sartori, Peter Inorganic Chemistry, 1991 , vol. 30, p. 2157 - 2161

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Citation Number: 16

Abstract

The oN (cI) F+ AsF6-and ON (CFJF+ AsF; salts are prepared by oxidative fluorination of ONCI and ONCF3 with N2F+ AsF (. Methylation of ONCF, with CH3F and AsFJ gives ON (cH3) CF3+ AsF6-, which in the solid state exists as the enol tautomer hydroxylimmonium salt HON (CH2) CF3+ AsF6-, triclinic, of space group PT with a= 5.063 (I) A, b= 7.757 (3) A, c= 10.429 (2) A, CY= 86.75 (2) O, fl= 89.34 (2) O, and y= 74.12 (2)". The framework of the ...