Journal of fluorine chemistry

Preparation of trifluoromethylated allylic alcohols from trifluoroacetaldehyde and organometallic compounds

N Ishikawa, GK Moon, T Kitazume, KC Sam

Index: Ishikawa, Nobuo; Koh, Moon Gyu; Kitazume, Tomoya; Choi, Sam Kwon Journal of Fluorine Chemistry, 1984 , vol. 24, p. 419 - 430

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Citation Number: 43

Abstract

Abstract A number of allylic alcohols bearing a trifluoromethyl group at the α-or γ-position, and α-trifluoromethylated γ-enols and-ynols were prepared by the reaction of trifluoroacetaldehyde with a variety of organometallic compounds. Most of the Reformatsky- or Grignard-type reactions required promotion by ultrasonic irradiation.