Chemistry Letters

Oxovanadium (IV) Complex Catalyzed Oxygenation of. ALPHA.,. BETA.-Unsaturated Carboxamide into 2, 3-Epoxycarboxamide with Molecular Oxygen and an …

S Inoki, T Takai, T Yamada, T Mukaiyama

Index: Inoki, Satoshi; Takai, Toshihiro; Yamada, Tohru; Mukaiyama, Teruaki Chemistry Letters, 1991 , # 6 p. 941 - 944

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Citation Number: 20

Abstract

In the presence of a catalytic amount of bis (1, 3-diketonato) oxovanadium (IV) complex, epoxidation of α, β-unsaturated carboxamides with molecular oxygen and an aldehyde proceeds smoothly at room temperature to give the corresponding 2, 3-epoxycarboxamides in good yields.