Helvetica Chimica Acta

Nachbargruppeneffekte bei massenspektrometrischen Fragmentierungsreaktionen: substituierte 1, 3??Diaminopropan??Derivate. 17. Mitteilung über das …

E Lerch, M Hesse

Index: Lerch,E.; Hesse,M. Helvetica Chimica Acta, 1972 , vol. 55, p. 1883 - 1897

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Abstract

Abstract The mass spectrometric behaviour of the 1, 3-diaminopropane derivative 4a (3, 7- diacetyl-3, 7-diazadodecane) was investigated with regard to the fragmentation reactions of N, N′, N ″-triacetylspermidine (1), as model for the 1, 3-diaminopropane part. It was established that the degradation reactions in 4a and 1 are essentially the same and mainly due to the interaction of two N-acetyl groups. Thereby it is established that the most ...