Synthesis and luminescence properties of new red-shifted absorption lanthanide (III) chelates suitable for peptide and protein labelling

…, S Poupart, M Hamon, JB Langlois, N Plé…

Index: Maindron, Nicolas; Poupart, Severine; Hamon, Maxime; Langlois, Jean-Baptiste; Ple, Nelly; Jean, Ludovic; Romieu, Anthony; Renard, Pierre-Yves Organic and Biomolecular Chemistry, 2011 , vol. 9, # 7 p. 2357 - 2370

Full Text: HTML

Citation Number: 10

Abstract

The synthesis and photo-physical properties of an original bis-pyridinylpyrazine chromophore efficiently sensitising europium (III) and samarium (III) are described. The corresponding lanthanide (III) complexes display in aqueous solutions a maximum excitation wavelength which is significantly red-shifted compared to the usual terpyridine- based chelates, and a valuable luminescence brightness above 2 000 dm3 mol− 1 cm− 1 ...