Mechanistic aspects of a homogeneous carbon monoxide hydrogenation catalyst-tetrairidium dodecacarbonyl in molten aluminum chloride-sodium chloride

JP Collman, JI Brauman, G Tustin…

Index: Journal of the American Chemical Society, , vol. 105, # 12 p. 3913 - 3922

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Citation Number: 27

Abstract

... 0 1983 American Chemical Society Page 2. ... It was our hope that a wide-ranging kinetic study would enable us to determine which of three plausible reaction mechanisms was operating: (1) a direct ... Ir4(CO)12 was pur- chased from Strem Chemicals and Pressure Chemical Co. ...