Oxidation in three-liquid-phase microemulsion systems using “Balanced Catalytic Surfactants”

V Nardello-Rataj, L Caron, C Borde…

Index: Nardello-Rataj, Veronique; Caron, Laurent; Borde, Cedric; Aubry, Jean-Marie Journal of the American Chemical Society, 2008 , vol. 130, # 45 p. 14914 - 14915

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Citation Number: 37

Abstract

A series of “Balanced Catalytic Surfactants”(BCS)[(C n) 2N (C1) 2] 2MoO4 (n= 8, 9, 10, 12) based on amphiphilic double-tailed quaternary ammonium with molybdate as a counterion has been developed for the dark singlet [4+ 2] cyclooxygenation of organic substrates in three-liquid-phase microemulsion systems. These cationic surfactants form three-liquid- phase microemulsion systems at room temperature in the presence of an appropriate ...