Mercaptoethylation. I. Mercaptoethylation of Amines with Ethylene Monothiolcarbonate

DD Reynolds, MK MASSAD, DL Fields…

Index: Reynolds,D.D. et al. Journal of Organic Chemistry, 1961 , vol. 26, p. 5109 - 5110

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Citation Number: 13

Abstract

(6) DD Reynolds, J, Am. Chem. kc.,? 9, 4951.(19.57). carbonate (11)(Eq. 1). The ease of this preparation suggested the possibility of the reaction of I1 with primary and secondary amines to form I without prior isolation of the ethylene sulfide (Eq. 2). This possibility was realized for moderately to strongly basic organic amines. The results obtained for a few representative examples are tabulated in Table I. The experimental procedure involved ...