Tetrahedron

Indium-mediated Reformatsky–Claisen rearrangement

…, N Koyama, Y Nishino, K Takahashi, S Hatakeyama

Index: Ishihara, Jun; Watanabe, Yuki; Koyama, Noriko; Nishino, Yukihiro; Takahashi, Keisuke; Hatakeyama, Susumi Tetrahedron, 2011 , vol. 67, # 20 p. 3659 - 3667

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Citation Number: 6

Abstract

Development of new methods for the stereoselective carbon–carbon bond formation has been important in the creation of useful molecules, such as drugs and other chemical entities. The [3,3]-sigmatropic rearrangements are reliable for selective bond formation, in particular, the Claisen rearrangement is one of the most competent methods to provide useful building blocks for the synthesis of natural products. 1, 1a, 1b, 1c and 1d The versatile utilities of their products ...