Tetrahedron letters

The generation and sigmatropic rearrangement of a derivative of vinyl-TMM (2, 5-dimethyl-3-isopropyl-4-isopropylidenehex-2-en-1, 5-diyl)

RJ Bushby, S Mann

Index: Bushby, Richard J.; Mann, Stephen Tetrahedron Letters, 1986 ,  vol. 27,  # 18  p. 2057 - 2060

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Citation Number: 4

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The thermal rearrangement of 2,5-dimethyl-3-isopropyl-4-isopropylidenehex-2-en-1,5-diyl to 4-isopropyl-3-isopropylidene-2,5-dimethylhexa-1,4-diene involves a 1,6-sigmatroplo shift of hydrogen which may occur in an antarafacial manner. ... From the reaction of acetyl ...