Tetrahedron letters

Free radical-promoted conjugate addition of activated bromo compounds using titanocene (III) chloride as the radical initiator

SK Mandal, S Jana, SC Roy

Index: Mandal, Samir Kumar; Jana, Samaraesh; Roy, Subhas Chandra Tetrahedron Letters, 2005 , vol. 46, # 36 p. 6115 - 6117

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Citation Number: 16

Abstract

Free radical-promoted conjugate addition of activated bromo compounds to α, β-unsaturated ketones and reactive α, β-unsaturated esters has been described using titanocene (III) chloride (Cp2TiCl) as the radical initiator. Cp2TiCl was prepared in situ from commercially available Cp2TiCl2 and activated zinc dust in THF.

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