Journal of the American Chemical Society

Evidences for the Direct Field Effect. II. 1 The Alkaline Rearrangement of Fluorosubstituted α-Diketones2

GG Smith, GO Larson

Index: Smith,G.G.; Larson,G.O. Journal of the American Chemical Society, 1960 , vol. 82, p. 99 - 104

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Citation Number: 7

Abstract

Previous papers hive reported the migratory ratios in the alkaline rearrangement of substituted benzils and phenanthrenequinones. l,'l A very marked proxiniity effect was noted in the rearrangement of 2-chlorobenzil,'l-chlorophenanthrenequinone'and Z-methylben~ il.~~~~~ The migration ratios in the alkaline rearrangement of 2-, 3-and 4-fluorobenzil and 1- fluorophenanthrenequinone have been determined as an extension of this study. The ...

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