Reactivity of cis-bis (acetylacetonato) dichlorotitanium (IV) towards hydroxy-containing ligands: isolation and characterisation of products†

P áVenkateshwara Rao, CP Rao…

Index: Rao, P. Venkateshwara; Rao, Chebrolu Pulla; Wegelius, Elina K.; Kolehmainen, Erkki; Rissanen, Kari Journal of the Chemical Society - Dalton Transactions, 1999 , # 24 p. 4469 - 4474

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Abstract

The reactivity of cis-[Ti (acac) 2Cl2] with a number of OH containing ligands has been explored. Corresponding products have been synthesized, isolated and characterised. Three dimensional structures of some of the products were established by single crystal X- ray diffraction. The reactivity of these ligands towards non-oxo titanium centres has been found to be different from that of oxometal centres of VV, MoVI and UVI. All the products of ...