Chemistry Letters

Some carbanionic reactions of α-chloroallyl sulfones

A Jonczyk, T Radwan-Pytlewski

Index: Jonczyk, Andrzej; Radwan-Pytlewski, Tadeusz Chemistry Letters, 1983 , p. 1557 - 1560

Full Text: HTML

Citation Number: 3

Abstract

The chlorination of 3-methyl-2-butenyl phenyl sulfone with either hexachloroethane or 1, 1- dichloro-3-methyl-2-butenyl phenyl sulfone in basic medium gives rise to 1-chloro-3-methyl- 2-butenyl phenyl sulfone which in turn reacts in situ with electrophilic compounds to give a variety of products in good yields.

 Related Synthetic Route
3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

nitrobenzene Structure

98-95-3

nitrobenzene

~51%

1-[1-(benzenesulfonyl)-3-methylbut-2-enyl]-4-nitrobenzene Structure

88958-90-1

1-[1-(benzenesu...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

(3-chloro-5-methylhex-4-en-3-yl)sulfonylbenzene Structure

88958-75-2

(3-chloro-5-met...

Bromoethane Structure

74-96-4

Bromoethane

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

~79%

(3-chloro-5-methylhex-4-en-3-yl)sulfonylbenzene Structure

88958-75-2

(3-chloro-5-met...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

(4-chloro-2-methyloct-2-en-4-yl)sulfonylbenzene Structure

88958-76-3

(4-chloro-2-met...

1-Bromobutane Structure

109-65-9

1-Bromobutane

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

~60%

(4-chloro-2-methyloct-2-en-4-yl)sulfonylbenzene Structure

88958-76-3

(4-chloro-2-met...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

[2-(benzenesulfonyl)-2-chloro-4-methylpent-3-enyl]benzene Structure

88958-77-4

[2-(benzenesulf...

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

Benzyl chloride Structure

100-44-7

Benzyl chloride

~67%

[2-(benzenesulfonyl)-2-chloro-4-methylpent-3-enyl]benzene Structure

88958-77-4

[2-(benzenesulf...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

2-Nitrochlorobenzene Structure

88-73-3

2-Nitrochlorobenzene

~51%

4-[1-(benzenesulfonyl)-3-methylbut-2-enyl]-2-chloro-1-nitrobenzene Structure

88958-91-2

4-[1-(benzenesu...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

1-[1-(benzenesulfonyl)-3-methylbut-2-enyl]-4-nitronaphthalene Structure

88958-93-4

1-[1-(benzenesu...

1-Nitronaphthalene Structure

86-57-7

1-Nitronaphthalene

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

~30%

1-[1-(benzenesulfonyl)-3-methylbut-2-enyl]-4-nitronaphthalene Structure

88958-93-4

1-[1-(benzenesu...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

4-(benzenesulfonyl)-4-chloro-6-methylhept-5-enenitrile Structure

88958-79-6

4-(benzenesulfo...

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

Acrylonitrile Structure

107-13-1

Acrylonitrile

~76%

4-(benzenesulfonyl)-4-chloro-6-methylhept-5-enenitrile Structure

88958-79-6

4-(benzenesulfo...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

4-(benzenesulfonyl)-4-chloro-6-methylhept-5-enoic acid Structure

88958-81-0

4-(benzenesulfo...

tert-Butyl acrylate Structure

1663-39-4

tert-Butyl acrylate

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

~%

4-(benzenesulfonyl)-4-chloro-6-methylhept-5-enoic acid Structure

88958-81-0

4-(benzenesulfo...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

2-(benzenesulfonyl)-2-(2-methylprop-1-enyl)-3-phenyloxirane Structure

88958-82-1

2-(benzenesulfo...

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

Benzaldehyde Structure

100-52-7

Benzaldehyde

~91%

2-(benzenesulfonyl)-2-(2-methylprop-1-enyl)-3-phenyloxirane Structure

88958-82-1

2-(benzenesulfo...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

2-(benzenesulfonyl)-2-(2-methylprop-1-enyl)-3-naphthalen-2-yloxirane Structure

88958-84-3

2-(benzenesulfo...

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

2-Naphthaldehyde Structure

66-99-9

2-Naphthaldehyde

~96%

2-(benzenesulfonyl)-2-(2-methylprop-1-enyl)-3-naphthalen-2-yloxirane Structure

88958-84-3

2-(benzenesulfo...

3-methylbut-2-enylsulfonylbenzene Structure

15874-80-3

3-methylbut-2-e...

~%

1-(benzenesulfonyl)-1-(4-methoxyphenyl)-4-methylpent-3-en-2-one Structure

88958-85-4

1-(benzenesulfo...

2-Benzenesulfonyl-3-(4-methoxy-phenyl)-2-(2-methyl-propenyl)-oxirane Structure

88958-86-5

2-Benzenesulfon...

~65%

1-(benzenesulfonyl)-1-(4-methoxyphenyl)-4-methylpent-3-en-2-one Structure

88958-85-4

1-(benzenesulfo...

(1-chloro-3-methylbut-2-enyl)sulfonylbenzene Structure

84602-95-9

(1-chloro-3-met...

~%

1-(benzenesulfonyl)-1-(4-methoxyphenyl)-4-methylpent-3-en-2-one Structure

88958-85-4

1-(benzenesulfo...


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