Tetrahedron letters

Preparation and chemistry of stable azidoiodinanes: 1-Azido-3, 3-bis (trifluoromethyl)-3-(1H)-1, 2-benziodoxol and 1-Azido-1, 2-benziodoxol-3-(1H)-one

VV Zhdankin, CJ Kuehl, AP Krasutsky, MS Formaneck…

Index: Zhdankin, Viktor V.; Kuehl, Chris J.; Krasutsky, Alexei P.; Formaneck, Mark S.; Bolz, Jason T. Tetrahedron Letters, 1994 , vol. 35, # 52 p. 9677 - 9680

Full Text: HTML

Citation Number: 48

Abstract

Abstract Azidoiodinanes 2, 4, 6 can be prepared from benziodoxols 1, 3 and trimethylsilyl azide in the form of stable, crystalline compounds. These compounds are potentially useful reagents for electrophilic azidonation of organic substrates. For example, reaction of azide 6 with cyclohexene affords 2-azidocyclohexanone 7 in moderate yield.