Synthesis of bicyclo [n. 2.1] bridgehead alkenes acetoxy substituted at the opposite bridgehead position

…, Y Fukuda, K Kakiuchi, Y Odaira

Index: Tobe, Yoshito; Fukuda, Yasushi; Kakiuchi, Kiyomi; Odaira, Yoshinobu Journal of Organic Chemistry, 1984 , vol. 49, # 11 p. 2012 - 2015

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Citation Number: 12

Abstract

Bridgehead alkenes containing a functional group at the opposite bridgehead position are of considerable interest from theoretical and synthetic points of view as models for examination of the effect of the substituents on the properties of the strained double bond'and as synthetic precursors of more strained bridgehead dienes. 2 Concerning bicyclo [n. 2.1] bridgehead alkenes, only the parent hydrocarbons of the bicyclo [4.2. 1] system have been ...