Experimental and theoretical studies on bis (chlorocarbonyl) trisulfane, ClC (O) SSSC (O) Cl

…, MV Cozzarín, CO Della Védova, RM Romano

Index: Tobon, Yeny A.; Cozzarin, Melina V.; Della Vedova, Carlos O.; Romano, Rosana M. Journal of Molecular Structure, 2009 , vol. 930, # 1-3 p. 37 - 42

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Abstract

Bis (chlorocarbonyl) trisulfane, ClC (O) SSSC (O) Cl, was prepared by the reaction of (CH3) 2CHOC (S) SC (S) OCH (CH3) 2 and SO2Cl2 at 65° C. The compound was characterized and identified by vibrational spectroscopy, GC–MS, matrix isolation and photochemical studies as well as by quantum chemical calculations. Matrix photochemical studies and vibrational spectra were interpreted in terms of the presence of three forms with syn- ...